What is acrylate oligomer?

Urethane acrylate oligomers are a desired ingredient in free radically cured formulations as they provide chemical resistance, heat resistance, water resistance and adhesion to name a few. The chemical nature and structure of these oligomers determine the physical properties obtained upon curing or polymerization.

What is polyurethane acrylate?

Polyurethane acrylates (PUAs) were widely used as oligomers to control the polymerization kinetic and mechanical properties for UV coatings, due to their excellent physical and chemical properties such as adhesion to substrates, impact property, flexibility, chemical and scratch resistance and weatherability [5], [6].

Is urethane acrylate toxic?

In general, UV/EB curing acrylates have low chronic toxicity, but they can cause acute skin and eye irritation or burns. Since they do not cause immediate irritation, exposure can go unnoticed. Some individuals may also become sensitized to these chemicals as a result of contact.

What is urethane acrylate resin?

Urethane-acrylate resins. They are replacing fireproof polyester resins thanks to its better properties: mechanical, reactivity, fire resistance. They are specially designed for applications in closed mould: RTM, infusion and pultrusion. Greater rigidity than polyester and vinyl ester resins.

What is aliphatic urethane acrylate?

Aliphatic Urethane Acrylate SU 5270 is a di-functional aliphatic urethane acrylate oligomer designed to provide flexibility, adhesion, toughness, and abrasion resistance. Common applications of this product include metal coatings, plastic coatings, pigment coatings for wood, and screen inks.

What is acrylate monomer?

Acrylate monomers are usually esters which contain vinyl groups, that is, two carbon atoms double-bonded to each other, directly attached to the carbonyl carbon of the ester group. Some acrylates have an extra methyl group attached to the alpha carbon, and these are called methacrylates.

How do you make polyurethane acrylate?

UV-curable polyurethane acrylates have been synthesized from polyester polyol (1,6-hexanediol, adipic acid and ethylene glycol), toluene diisocyanate and three types of reactive diluents i.e., ethoxylated phenol monoacrylate (EOPA), 1,6-hexanediol -diacrylate (HDDA) and trimethylolpropane triacrylate (TMPTA).

What is a substitute for monomer?

What is a good substitute for monomer? A good substitute is polyester resin. A peroxide is added to a polymer to create the resin that can be cast as easily as acrylics. Polyester resins harden at room temperature and with a green color that is transparent, but not always preferred.

What is an example of an acrylate?

Acrylate monomers, used to form acrylate polymers, are based on the structure of acrylic acid, which consists of a vinyl group and a carboxylic acid ester end or a nitrile. Other examples of acrylate monomers are: Methacrylates. Methyl acrylate.

How are acrylates made?

Acrylates are industrially prepared by treating acrylic acid with the corresponding alcohol in presence of a catalyst. The reaction with lower alcohols (methanol, ethanol) takes place at 100–120 °C with acidic heterogeneous catalysts (cation exchanger).